My approach was just to look only at stats compiled prior to the 1901 season. That yields this list:
1. Kid Nichols
2. Cy Young
3. John Clarkson
4. Tim Keefe
5. Dan Brouthers
6. Roger Connor
7. Cap Anson
8. Jim McCormick
9. Hoss Radbourn
10. Bob Caruthers
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